A NOVEL OXIDATIVE DECARBOXYLATION OF ALPHA-SUBSTITUTED ALPHA-HYDROXY ACIDS BY A FUNCTIONALIZED OXIDATION-ACTIVE FLAVIN MIMIC IN THE PRESENCE OF A METAL-ION IN T-BUTYL ALCOHOL

Authors
ANDO N OSAWA Y NABESHIMA T YANO Y
Citation
N. Ando et al., A NOVEL OXIDATIVE DECARBOXYLATION OF ALPHA-SUBSTITUTED ALPHA-HYDROXY ACIDS BY A FUNCTIONALIZED OXIDATION-ACTIVE FLAVIN MIMIC IN THE PRESENCE OF A METAL-ION IN T-BUTYL ALCOHOL, Chemistry Letters, (5), 1996, pp. 381-382
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
5
Year of publication
1996
Pages
381 - 382
Database
ISI
SICI code
0366-7022(1996):5<381:ANODOA>2.0.ZU;2-F
Abstract
A benzo-dipteridine bearing a bipyridin-6-ylmethyl moiety (6-bpy-BDPox ) was found to conduct oxidative decarboxylation of alpha-methyl mande lic and benzylic acids to give acetophenone and benzophenone and the r educed form (6-bpy-BDPred) in the presence of Ni2+ and DBU in t-BuOH.