TRICHLOROSILANE-DIMETHYLFORMAMIDE (CL3SIH-DMF) AS AN EFFICIENT REDUCING AGENT - REDUCTION OF ALDEHYDES AND IMINES AND REDUCTIVE AMINATION OF ALDEHYDES UNDER MILD CONDITIONS USING HYPERVALENT HYDRIDOSILICATES

Authors
KOBAYASHI S YASUDA M HACHIYA I
Citation
S. Kobayashi et al., TRICHLOROSILANE-DIMETHYLFORMAMIDE (CL3SIH-DMF) AS AN EFFICIENT REDUCING AGENT - REDUCTION OF ALDEHYDES AND IMINES AND REDUCTIVE AMINATION OF ALDEHYDES UNDER MILD CONDITIONS USING HYPERVALENT HYDRIDOSILICATES, Chemistry Letters, (5), 1996, pp. 407-408
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
5
Year of publication
1996
Pages
407 - 408
Database
ISI
SICI code
0366-7022(1996):5<407:T(AAER>2.0.ZU;2-U
Abstract
Trichlorosilane-dimethylformamide (Cl3SiH-DMF) was found to be an effe ctive reducing agent for reduction of aldehydes to alcohols, imines to amines, and also reductive amination of aldehydes. Hypervalent silica tes are active species, which enable efficient reduction under mild co nditions.