ENANTIOSELECTIVE REARRANGEMENT OF EXO-NORBORNENE OXIDE TO NORTRICYCLANOL

Authors
HODGSON DM WISEDALE R
Citation
Dm. Hodgson et R. Wisedale, ENANTIOSELECTIVE REARRANGEMENT OF EXO-NORBORNENE OXIDE TO NORTRICYCLANOL, Tetrahedron : asymmetry, 7(5), 1996, pp. 1275-1276
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear","Chemistry Physical
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
7
Issue
5
Year of publication
1996
Pages
1275 - 1276
Database
ISI
SICI code
0957-4166(1996)7:5<1275:EROEOT>2.0.ZU;2-L
Abstract
The enantioselective alpha-deprotonation-rearrangement of exo-norborne ne oxide 1 to (-)-nortricyclanol 2 in up to 52% ee using a nonracemic lithium amide, or an organolithium in the presence of (-)-sparteine, i s described. Copyright (C) 1996 Elsevier Science Ltd