Arylene bisazo resorcinol dyes IIIa-e were prepared and polycondensed
with formaldehyde in the presence of aqueous oxalic acid. The resultin
g polymeric dyes IVa-e were characterized by yield, melting point, col
our, elemental analysis and visible and IR spectroscopy. The thermal p
roperties of polymeric dyes were examined by thermogravimetric analysi
s. Their dyeing performance on nylon and polyester was assessed. The d
yeing on nylon and polyester had yellow, orange, red and brown shades
with moderate to good, light and wash fastness. Polymerization of bisa
zo dyes IIIa-e with formaldehyde on dyed nylon and polyester have also
been carried out. The dyeing properties of polymeric dyes were compar
ed with the dyes polymerized on nylon and polyester.