SYNTHESIS OF EPOXYCONTAINING SILICONORGANIC COMPOUNDS

Citation
Lm. Khananashvili et al., SYNTHESIS OF EPOXYCONTAINING SILICONORGANIC COMPOUNDS, International journal of polymeric materials, 28(1-4), 1995, pp. 43-49
Citations number
3
Categorie Soggetti
Polymer Sciences","Engineering, Chemical
ISSN journal
00914037
Volume
28
Issue
1-4
Year of publication
1995
Pages
43 - 49
Database
ISI
SICI code
0091-4037(1995)28:1-4<43:SOESC>2.0.ZU;2-O
Abstract
Epoxycompounds containing the methyl, phenyl, vinyl, chlormethyl, thie nyl and chlorthienyl radicals with molecules containing one siloxane o r cyclosiloxane, or two and more siloxane fragments are synthesised fo r the first time by the hydrosililization of alylglicidyl ester with o rganohydrosilanes or siloxanes in the presence of Speier catalizator H 2PtCl6 The reaction of hydrosililization is studied using infrared spe ctroscopy and gas-liquid chromatography method. The anionic polymeriza tion of epoxi-compounds containing cyclosiloxane fragments using pha,b eta-bis(tetramethilammonium)dimethilsilanolat is carried out.