SYNTHESIS OF 2,3,6,7-TETRAHYDRO-1H-1,4-DIAZEPINES AND 2,3,4,5,6,7-HEXAHYDRO-1H-1,4-DIAZEPINES VIA A TANDEM MICHAEL-TYPE ADDITION INTRAMOLECULAR AZA-WITTIG SEQUENCE

Authors
BENALIL A GUERIN A CARBONI B VAULTIER M
Citation
A. Benalil et al., SYNTHESIS OF 2,3,6,7-TETRAHYDRO-1H-1,4-DIAZEPINES AND 2,3,4,5,6,7-HEXAHYDRO-1H-1,4-DIAZEPINES VIA A TANDEM MICHAEL-TYPE ADDITION INTRAMOLECULAR AZA-WITTIG SEQUENCE, Journal of the Chemical Society. Perkin transactions. I, (9), 1993, pp. 1061-1064
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
9
Year of publication
1993
Pages
1061 - 1064
Database
ISI
SICI code
0300-922X(1993):9<1061:SO2A2>2.0.ZU;2-D
Abstract
Intramolecular aza-Wittig reaction of azides derived from 1,2-amino az ides and alpha,beta-unsaturated ketones leads to 2,3,6,7-tetrahydro-1 H-1,4-diazepines. Reduction of these compounds with lithium aluminium hydride affords the corresponding saturated heterocycles.