ORGANIC NITRO-COMPOUNDS AS LIGANDS - A COMPARISON BETWEEN THE LIGAND BEHAVIOR OF MENO2 AND PHNO2 TOWARDS ALCL3

Authors
LANFRANCHI M PELLINGHELLI MA PREDIERI G BIGI F MAGGI R SARTORI G
Citation
M. Lanfranchi et al., ORGANIC NITRO-COMPOUNDS AS LIGANDS - A COMPARISON BETWEEN THE LIGAND BEHAVIOR OF MENO2 AND PHNO2 TOWARDS ALCL3, Journal of the Chemical Society. Dalton transactions, (9), 1993, pp. 1463-1464
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
9
Year of publication
1993
Pages
1463 - 1464
Database
ISI
SICI code
0300-9246(1993):9<1463:ONAL-A>2.0.ZU;2-R
Abstract
The crystal-structure analyses of the complexes [AlCl3(RNO2)] (R = Me or Ph) and NM R data in solution suggest a stronger Al-O co-ordinative interaction in the case of nitrobenzene compared to nitromethane; thi s could account for the dramatic solvent effects observed during certa in electrophilic acylation processes involving AlCl3 as a promoter.