This paper summarises the background to work carried out at the Univer
sity of Twente on the use of niobia as a catalyst for the oxidative de
hydrogenation of propane to propylene and discusses the development of
promoted niobia catalysts for this reaction. Results are also present
ed which illustrate the use of niobia in catalysts for other reactions
such as the oxidative coupling of methane, the oxidative dehydrogenat
ion of ethane and the oxidative dehydrogenation of methanol. It appear
s that niobia and niobia-modified catalysts, when used in high-tempera
ture oxidation processes, can exhibit relatively high selectivities co
mpared with more conventional catalysts.