K. Praefcke et al., LIQUID-CRYSTALLINE COMPOUNDS .76. BIS-1,3-DIOL TYPE LIQUID-CRYSTALS FROM PENTAERYTHRITOL, Liquid crystals, 13(4), 1993, pp. 551-559
Several esters and ethers of pentaerythritol have been prepared. Four
of them, containing each a 1,4-trans-disubstituted cyclo-hexane unit a
nd three hydroxyl functions, emerge as examples of a novel type of the
rmotropic, intermolecularly hydrogen bridge-supported multiol mesogens
exhibiting the smectic A phase. A new case of a heteroatom effect pre
venting mesophase formation by causing stable intramolecular hydrogen
bonding situations will also be discussed.