CHEMICAL KINETIC MODELING OF THE SUPERCRITICAL-WATER OXIDATION OF METHANOL

Authors
DAGAUT P CATHONNET M BOETTNER JC
Citation
P. Dagaut et al., CHEMICAL KINETIC MODELING OF THE SUPERCRITICAL-WATER OXIDATION OF METHANOL, The Journal of supercritical fluids, 9(1), 1996, pp. 33-42
Citations number
23
Categorie Soggetti
Chemistry Physical","Engineering, Chemical
Journal title
The Journal of supercritical fluids → ACNP
ISSN journal
08968446
Volume
9
Issue
1
Year of publication
1996
Pages
33 - 42
Database
ISI
SICI code
0896-8446(1996)9:1<33:CKMOTS>2.0.ZU;2-W
Abstract
The kinetics of the supercritical oxidation of methanol was modeled us ing a detailed chemical kinetic reaction mechanism initially validated for the supercritical-water oxidation of hydrogen, carbon monoxide, a nd methane. The concentration profiles of reactants and products measu red in a plug flow reactor at MIT have been used to validate a detaile d kinetic reaction mechanism in supercritical conditions.