The time-dependent Schrodinger equation is a square-preserving and sym
plectic (SPS) transformation, The canonical equations of quantum syste
ms are deduced by using eigenfunction expansion, The normal-square of
wavefunction of the quantum systems is an invariant integral of the ca
nonical equations and then the symplectic schemes that based on both C
ayley transformation and diagonal Pade approximation to exp(x) are als
o square-preserving, The evaluated example show that the SPS approach
is reasonable and effective for solving time-evolution of quantum syst
em.