Slow atoms from a magneto-optical trap are used to study diffraction f
rom a near-resonant standing-wave light field. Long interaction times
make it possible to observe unidirectional Bragg scattering. In partic
ular, the Pendellosung interference effect between two resonant moment
um states is demonstrated for first- and second-order diffraction. The
oscillation frequency of second-order scattering shows a transition f
rom a four-photon-type process at low light intensity to a two-photon-
type process at higher intensity. The data are in quantitative agreeme
nt with a theoretical description which takes into account lowest-ener
gy momentum states.