P. Spatenka et H. Suhr, USE OF LANGMUIR PROBES FOR MONITORING OF PRECURSOR CONCENTRATIONS DURING PLASMA ACTIVATED CHEMICAL-VAPOR DEPOSITION OF HARD COATINGS, Applied physics. A, Solids and surfaces, 56(5), 1993, pp. 443-444
Langmuir-probe characteristics were measured during the deposition of
hard zirconium nitride films in H-2 plasmas with tetrakis(diethylamido
)-zirconium -Zr[N(C2H5)2]4- as a precursor. A combination of fast repe
atable probe sweeps and hysteresis measurements indicated undisturbed
characteristics for approximately 1 h. Since the electron concentratio
n is highly dependent on the partial pressure of the precursor it is p
ossible to use probes as sensors to monitor precursor concentration in
a discharge.