The morphology and conductivity of polymer electrolytes based on PEO a
re often substantially modified by the presence of water. A number of
different approaches have commonly been used to eliminate water from p
olymer electrolyte films. The work reported here extends our earlier i
nvestigations of the use of microwaves for the rapid drying of solvent
cast polymer electrolyte films. Films of PEO(n):NiBr2 and PEO(n):ZnCl
2 have been prepared by normal casting techniques and then studied usi
ng EXAFS, DSC and ac conductivity measurements.