The feasibility of graded-index waveguiding structures by anion-exchan
ge on glass substrates has been shown for the first time to our knowle
dge. A new technology has been developed to produce integrated optical
components on fluoride glass substrates by anionic exchange from eith
er water or heavy water vapor-containing gas flows.D2O-made waveguides
operating from UV up to 1.8 mu m, and from 2.55 to 3.6 mu m, have bee
n proved to be easily achievable. The refractive index profile of one
planar waveguide has been determined, revealing 10 guided modes at 0.6
33 mu m, which is widely better than the best results previously obtai
ned by cation-exchange.