CONCERNING THE INCORPORATION OF DIVALENT-CATIONS INTO THE HIGH-TEMPERATURE MODIFICATION OF LI2SO4

Authors
FEDOROV PP
Citation
Pp. Fedorov, CONCERNING THE INCORPORATION OF DIVALENT-CATIONS INTO THE HIGH-TEMPERATURE MODIFICATION OF LI2SO4, Solid state ionics, 84(1-2), 1996, pp. 113-115
Citations number
18
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
Solid state ionics → ACNP
ISSN journal
01672738
Volume
84
Issue
1-2
Year of publication
1996
Pages
113 - 115
Database
ISI
SICI code
0167-2738(1996)84:1-2<113:CTIODI>2.0.ZU;2-T
Abstract
The analysis of the solubility of MSO(4) in the high-temperature cubic modification of Li2SO4 reveals that divalent cations in the Li2SO4 st ructure can occupy either tetrahedral or octahedral positions. The for mer case is preferred for Be2+, and, to some extent, for Zn2+. For all the other divalent cations the octahedral positions are prefered in t he formation of the alpha-Li2SO4-based solid solutions.