C. Gondran et al., KINETICS OF SODIUM AND SILVER EXCHANGE ON A PEO(X)-NAI-(AGI)(0.25) BASED INTERNAL REFERENCE SYSTEM, Solid state ionics, 84(1-2), 1996, pp. 131-138
The ionic conductivity of the PEO(x)-NaI-(AgI)(0.25) system and electr
ical properties of the NASICON/PEO(x)-NaI-(AgI)(0.25) and Ag/PEO(x)-Na
I-(AgI)(0.25) interfaces are reported as a function of the temperature
and the composition. The interfacial resistances are less influenced
by the recrystallization process than is the ionic conductivity. The i
nterfacial resistances are related to the concentration of charge carr
iers while the ionic conductivity depends significantly on their mobil
ity.