SYNTHESIS OF POLY(1,4-PHENYLENEVINYLENE) DERIVATIVES CONTAINING NLO CHROMOPHORE WITHIN SIDE-CHAINS

Authors
MOON KJ LEE KS SHIM HK
Citation
Kj. Moon et al., SYNTHESIS OF POLY(1,4-PHENYLENEVINYLENE) DERIVATIVES CONTAINING NLO CHROMOPHORE WITHIN SIDE-CHAINS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 280, 1996, pp. 39-45
Citations number
10
Journal title
Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals → ACNP
ISSN journal
1058725X
Volume
280
Year of publication
1996
Pages
39 - 45
Database
ISI
SICI code
1058-725X(1996)280:<39:SOPDCN>2.0.ZU;2-W
Abstract
Poly(1,4-phenylenevinylene) derivative, 58-poly(NO2STMPV-co-IMPV), con sisting of -nitrostilben-4'-yl-oxy)propoxy}phenylenevinylene] (poly(NO 2STMPV)) and poly(2-isopropoxy-5-methoxy-1,4-phenylenevinylene) (poly( IMPV)) was synthesized through the Wessling's precursor method. Films of the precursor copolymers were eliminated either by way of thermal t reatment or using strong acidic conditions. The electrical conductivit ies of FeCl3-doped 58-poly(NO2STMPV-co-IMPV) were found to be between 10(-1)-10(-4) S/cm. The second-order nonlinear optical susceptibility (d(33)) of this copolymer was about 2.0 pm/V.