The effects of ion irradiation on superconducting BiSrCaCuO ultrathin
films were examined. Superconducting ultrathin films with a nearly thr
ee half-unit-cell thickness of similar to 50 Angstrom were prepared by
rf magnetron sputtering and a precisely controlled multistep heat tre
atment. The 100 keV Ar ion irradiation followed by short-time annealin
g of these ultrathin films was found to improve the zero-resistance cr
itical temperature T-c,T-0 in a significant manner. The T-c,T-0 improv
ement was marked in the case of low-T-c,T-0 multiphase films. The ion
beam modification of ultrathin films was interpreted in terms of Ar-io
n-induced atomic mixing and reordering within a specific volume contai
ning superconducting phases and nonsuperconducting impurity phases.