A crystal-field model for the electronic structure of the Er3+ ion in
silicon is presented. The parameters within the model are adjusted in
order that the Stark energy splittings within the f shell reproduce th
e observed spectral features in a Si:Er sample that is codoped with ni
trogen. The dominant crystal field possesses tetrahedral symmetry. Sev
eral additional spectral features are attributed to local mode vibrati
onal sidebands. From this analysis, I conclude that the role of the co
dopants is to isolate the Er ion so that the relaxation energy does no
t go into the production of lattice phonons. (C) 1996 American Institu
te of Physics.