Jl. Benton et al., THE MECHANISMS OF IRON GETTERING IN SILICON BY BORON ION-IMPLANTATION, Journal of the Electrochemical Society, 143(4), 1996, pp. 1406-1409
Boron implantation into silicon offers a unique system for studying th
e gettering mechanisms of Fe. The effectiveness of the gettering incre
ases as the high-energy B ion implantation dose changes from 4E12 to 4
E14 cm(-2), decreasing the Fe concentration in the near surface region
to below the deep level transient spectroscopy detection limit of 1E1
0 cm(-3) Fermi level-induced Fe solubility enhancement and Fermi level
-controlled Fe-B pairing combine to produce a relative partitioning fo
r Fe as high as 10(6), for temperatures less than 400 degrees C, in hi
gh B-doped implanted regions adjacent to regions of low B bulk doping.
Comparison studies show that in the time-temperature regimes typical
of Si device fabrication, B gettering is more effective than gettering
produced by Si implantation damage and more effective than trapping b
y a neutral impurity such as C.