Tn. Angelidis et Ka. Kydros, SEPARATION OF GOLD FROM IODINE-IODIDE SOLUTIONS BY CEMENTATION ON ZINC PARTICLES, Separation science and technology, 31(8), 1996, pp. 1105-1121
Separation of gold from iodine-iodide solutions by cementation on zinc
particles was studied. The effect of various parameters such as mixin
g rate, temperature, zinc particles size, and initial concentrations o
f gold-iodide complex and iodine were examined. The reaction was found
to be under diffusion control at the conditions studied. Due to iodin
e side reactions, excess zinc consumption and a subsequent retardation
of the cementation reaction rate were identified. A well-defined, con
ventional first-order kinetics model was established to explain the ex
perimental findings.