CARBENE COMPLEXES FROM COORDINATED BIS(DIPHENYLPHOSPHINO)METHANE - SYNTHESIS AND X-RAY STRUCTURE DETERMINATION OF THE REMARKABLE HETEROTRIMETALLIC DERIVATIVE [(FE(CNPH)4((PPH2)2C))2HG]I2

Authors
RUIZ J ARAUZ R RIERA V VIVANCO M GARCIAGRANDA S PEREZCARRENO E
Citation
J. Ruiz et al., CARBENE COMPLEXES FROM COORDINATED BIS(DIPHENYLPHOSPHINO)METHANE - SYNTHESIS AND X-RAY STRUCTURE DETERMINATION OF THE REMARKABLE HETEROTRIMETALLIC DERIVATIVE [(FE(CNPH)4((PPH2)2C))2HG]I2, Journal of the Chemical Society, Chemical Communications, (9), 1993, pp. 740-742
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1993
Pages
740 - 742
Database
ISI
SICI code
0022-4936(1993):9<740:CCFCB->2.0.ZU;2-P
Abstract
The bis(diphenylphosphino)methanide complexes fac-[Mn(CNBut)(CO)3{(PPh 2)2CH}] la and [Fe(CNPh)4{(PPh2)2CH}]ClO4 lb react with HgI2 and KOH t o give the heterotrimetallic bis(carbene)derivatives fac-[{Mn(CNBut)(C O)3((PPh2)2C)}2Hg] 4a and [{Fe(CNPh)4[(PPh2)2C])2Hg]I2 4b, respectivel y; the structure of 4b has been determined by X-ray analysis.