C-H ALLYLIC BOND-CLEAVAGE TO GENERATE AN ACTIVE HYDRIDOPALLADIUM SPECIES FOR THE ALKOXYCARBONYLATION OF ALKENES - X-RAY CRYSTAL-STRUCTURE OF [(PH3PCH2CH=CHPH)4(PDCL6)(SNCL6)]

Authors
CHENAL T NAIGRE R CIPRES I KALCK P DARAN JC VAISSERMANN J
Citation
T. Chenal et al., C-H ALLYLIC BOND-CLEAVAGE TO GENERATE AN ACTIVE HYDRIDOPALLADIUM SPECIES FOR THE ALKOXYCARBONYLATION OF ALKENES - X-RAY CRYSTAL-STRUCTURE OF [(PH3PCH2CH=CHPH)4(PDCL6)(SNCL6)], Journal of the Chemical Society, Chemical Communications, (9), 1993, pp. 747-750
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1993
Pages
747 - 750
Database
ISI
SICI code
0022-4936(1993):9<747:CABTGA>2.0.ZU;2-D
Abstract
On the basis of a reactivity study using various alkenes and of the X- ray crystal structure analysis of the title compound isolated from the alkoxycarbonylation reaction, the formation of an active Pd(H)(SnCl3) species, generated from the [PdCl2(PPh3)2]SnCl2-PPh3 system, is propo sed.