AN EFFICIENT PROCEDURE FOR PALLADIUM-CATALYZED HYDROFORMYLATION OF ARYL ENOL TRIFLATES/

Authors
KOTSUKI H DATTA PK SUENAGA H
Citation
H. Kotsuki et al., AN EFFICIENT PROCEDURE FOR PALLADIUM-CATALYZED HYDROFORMYLATION OF ARYL ENOL TRIFLATES/, Synthesis, (4), 1996, pp. 470
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
4
Year of publication
1996
Database
ISI
SICI code
0039-7881(1996):4<470:AEPFPH>2.0.ZU;2-W
Abstract
An efficient method for hydroformylation of aryl and enol trifluoromet hanesulfonates is presented. Their reaction with carbon monoxide, trio ctylsilane, and triethylamine in the presence of a catalytic amount of palladium acetate and 1,3-bis(diphenylphosphanyl)propane proceeds eff iciently to provide a variety of aromatic and alpha,beta-unsaturated a ldehydes.