CURTIUS REARRANGEMENT OF OMEGA-AZIDO ACID-CHLORIDES - ACCESS TO THE CORRESPONDING OMEGA-AZIDO SUBSTITUTED AMINES AND CARBAMATES, USEFUL BUILDING-BLOCKS FOR POLYAMINE SYNTHESES

Authors
KHOUKHI M VAULTIER M BENALIL A CARBONI B
Citation
M. Khoukhi et al., CURTIUS REARRANGEMENT OF OMEGA-AZIDO ACID-CHLORIDES - ACCESS TO THE CORRESPONDING OMEGA-AZIDO SUBSTITUTED AMINES AND CARBAMATES, USEFUL BUILDING-BLOCKS FOR POLYAMINE SYNTHESES, Synthesis, (4), 1996, pp. 483
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthesis → ACNP
ISSN journal
00397881
Issue
4
Year of publication
1996
Database
ISI
SICI code
0039-7881(1996):4<483:CROOA->2.0.ZU;2-S
Abstract
Treatment of omega-azido acid chlorides with trimethylsilyl azide affo rds omega-azido isocyanates which can be easily converted in good yiel ds to the corresponding omega-azidoamines or omega-azidocarbamates. 1, 3- and 1,4-Diamine dihydrochlorides can then be prepared by catalytic hydrogenation or reductive alkylation with an organodichloroborane.