ISOLATION OF A ZEROVALENT IRON DINITROGEN COMPLEX WITH 1,2-BIS(DIETHYLPHOSPHINO)ETHANE LIGANDS

Authors
KOMIYA S AKITA M YOZA A KASUGA N FUKUOKA A KAI Y
Citation
S. Komiya et al., ISOLATION OF A ZEROVALENT IRON DINITROGEN COMPLEX WITH 1,2-BIS(DIETHYLPHOSPHINO)ETHANE LIGANDS, Journal of the Chemical Society, Chemical Communications, (9), 1993, pp. 787-788
Citations number
8
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
9
Year of publication
1993
Pages
787 - 788
Database
ISI
SICI code
0022-4936(1993):9<787:IOAZID>2.0.ZU;2-#
Abstract
A zerovalent iron dinitrogen complex [Fe(N2)(depe)2] having 1,2-bis(di ethylphosphino)ethane ligands has been prepared by reduction of [FeCl2 (depe)2] with sodium-naphthalene in tetrahydrofuran under nitrogen at room temperature.