PHOTOIONIZATION AND DYNAMIC SOLVATION OF THE EXCITED-STATES OF 7-AZAINDOLE

The excited-state photophysics of the biological probe, 7-azaindole, a re examined in water and methanol. Electrons in a presolvated state ab sorbing in the infrared appear within the excitation pulse width of 13 0 fs. 330 +/- 100 fs is required for the presolvated electron to achie ve the spectrum characteristic of the completely solvated electron. An excited-state transient absorbance decays in approximately 350 fs for 7-azaindole and its methylated analog, N1-methyl-7-azaindole(1M7AI),i n the region 400-450 nm in water and methanol. The instantaneous appea rance of the electron in the infrared is attributed to the decay of th e 1L(b) excited-state that overlaps the 1L(a) excited state of 7-azain dole. The rapid decay of the excited-state transient absorbance is att ributed to preferential, dynamic solvation of the 1L(a) state. 7-Azain dole thus provides an interesting example of a molecule whose excited state is continuously and dynamically solvated but which also produces a species, e(aq)-, whose solvation appears to occur in a stepwise pro cess.