KINETIC-STUDIES ON PHOTODEPOSITION OF POLYDIACETYLENE THIN-FILMS FROMSOLUTION - PRELIMINARY DETERMINATION OF THE RATE LAW

Authors
PALEY MS ARMSTRONG S WITHEROW WK FRAZIER DO
Citation
Ms. Paley et al., KINETIC-STUDIES ON PHOTODEPOSITION OF POLYDIACETYLENE THIN-FILMS FROMSOLUTION - PRELIMINARY DETERMINATION OF THE RATE LAW, Chemistry of materials, 8(4), 1996, pp. 912-915
Citations number
8
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Chemistry of materials → ACNP
ISSN journal
08974756
Volume
8
Issue
4
Year of publication
1996
Pages
912 - 915
Database
ISI
SICI code
0897-4756(1996)8:4<912:KOPOPT>2.0.ZU;2-C
Abstract
Preliminary kinetic studies were undertaken on the photodeposition of thin films of a polydiacetylene derivative of 2-methyl-4-nitroaniline from monomer solutions onto quartz substrates, Solutions of the monome r, DAMNA, in 1,2-dichloroethane at various concentrations were irradia ted at 364 nm using an argon-ion laser at several intensities. It was found that the rate of polydiacetylene (PDAMNA) film photodeposition v aries linearly with UV light intensity and as the square root of monom er concentration.