The complex formation model has been used to extract the atomic level
interactions in liquid Sb-In alloys. The phase diagram, the concentrat
ion fluctuations and the chemical short range order parameter indicate
that the chemical complexes of the equiatomic composition (SbIn) exis
t in the liquid phase. The nature of interactions between Sb, In and t
he complexes (SbIn) in the liquid phase are attractive. The observed c
oncentration dependent behaviour of activity, H-M, G(xs)S(xs) and Scc(
0) have been successfully explained.