FUNCTIONALIZED POLY(EPSILON-CAPROLACTONE) AND COPOLYMERS WITH ETHYLENE-OXIDE THROUGH HETEROGENEOUS ANIONIC COORDINATED POLYMERIZATION - NMRCHARACTERIZATION AND CRYSTALLINITY

Authors
JACQUIER V MIOLA C LLAURO MF MONNET C HAMAIDE T
Citation
V. Jacquier et al., FUNCTIONALIZED POLY(EPSILON-CAPROLACTONE) AND COPOLYMERS WITH ETHYLENE-OXIDE THROUGH HETEROGENEOUS ANIONIC COORDINATED POLYMERIZATION - NMRCHARACTERIZATION AND CRYSTALLINITY, Macromolecular chemistry and physics, 197(4), 1996, pp. 1311-1324
Citations number
39
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular chemistry and physics → ACNP
ISSN journal
10221352
Volume
197
Issue
4
Year of publication
1996
Pages
1311 - 1324
Database
ISI
SICI code
1022-1352(1996)197:4<1311:FPACWE>2.0.ZU;2-5
Abstract
Functionalized poly(epsilon-caprolactone)s have been easily prepared b y using a new heterogeneous catalytic system consisting of aluminium a lcoholate supported on porous silica and the corresponding alcohol in excess. The polymers have been fully characterized by H-1 and C-13 NMR spectroscopy. Oligo(caprolactone-co-ethylene oxide)s have been synthe sized by the same catalytic system. The diad comonomer distribution as obtained by H-1 NMR suggests a blocky structure. In addition, low deg rees of crystallization have been determined by means of DSC.