PROTON NUCLEAR-MAGNETIC-RESONANCE DETERMINATION OF HEXAMETHYLENETETRAMINE IN THE PRESENCE OF FORMALDEHYDE AND URINE

Authors
MADSEN GL CRUMRINE DS JASELSKIS B
Citation
Gl. Madsen et al., PROTON NUCLEAR-MAGNETIC-RESONANCE DETERMINATION OF HEXAMETHYLENETETRAMINE IN THE PRESENCE OF FORMALDEHYDE AND URINE, Analyst, 121(4), 1996, pp. 567-570
Citations number
34
Categorie Soggetti
Chemistry Analytical
Journal title
Analyst → ACNP
ISSN journal
00032654
Volume
121
Issue
4
Year of publication
1996
Pages
567 - 570
Database
ISI
SICI code
0003-2654(1996)121:4<567:PNDOH>2.0.ZU;2-N
Abstract
A new proton NMR method has been developed for micro-amount determinat ion of aqueous hexamethylenetetramine (HMT) alone, in the presence of large amounts of formaldehyde, and in urine, The method is based on th e direct determination of HMT in [H-2(3)]acetonitrile containing aniso le as the internal reference standard. HMT is determined in the range 5-50 mu g using a 5 mm NMR tube.