SALTS OF THE [(NH2)PH(2)PNPPH(2)(NH2)](-STRUCTURE OF PH(2)PNPPH(2)(NH2)](2)[SBCL6]CL-CENTER-DOT-CHCL3() CATION AND THE CRYSTAL)

Authors
FORSTER GE BEGLEY MJ SOWERBY DB
Citation
Ge. Forster et al., SALTS OF THE [(NH2)PH(2)PNPPH(2)(NH2)](-STRUCTURE OF PH(2)PNPPH(2)(NH2)](2)[SBCL6]CL-CENTER-DOT-CHCL3() CATION AND THE CRYSTAL), Polyhedron, 15(13), 1996, pp. 2151-2157
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
15
Issue
13
Year of publication
1996
Pages
2151 - 2157
Database
ISI
SICI code
0277-5387(1996)15:13<2151:SOT[OP>2.0.ZU;2-Q
Abstract
A number of salts of the amidophosphazenyl-phosphonium cation, [(NH2)P h(2) PNPPh(2)(NH2)](+) (C+), including C[SbCl6], C[SbPh(2)Cl(4)], C[Sb Ph(2)Br(4)] and the double salt C-2[SbCl6]Cl, have been synthesized. U nsuccessful attempts to dehydrohalogenate these compounds to give hete rocyclophosphazenes are described, together with the crystal structure of the double salt.