PHOTOLYSIS OF 3-HYDROXY-2,3-DIHYDRO-2,1-BENZISOXAZOLE DERIVATIVES STUDIED BY EPR SPECTROSCOPY - COMPETING N-O AND C-O BOND SCISSION

Authors
SRIVASTAVA S FALVEY DE
Citation
S. Srivastava et De. Falvey, PHOTOLYSIS OF 3-HYDROXY-2,3-DIHYDRO-2,1-BENZISOXAZOLE DERIVATIVES STUDIED BY EPR SPECTROSCOPY - COMPETING N-O AND C-O BOND SCISSION, Tetrahedron letters, 37(17), 1996, pp. 2895-2898
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
17
Year of publication
1996
Pages
2895 - 2898
Database
ISI
SICI code
0040-4039(1996)37:17<2895:PO3DS>2.0.ZU;2-G
Abstract
Photolysis of 3-hydroxy-2,3-dihydro-2,1-benzisoxazole derivatives give s 2-acetylaniline derivatives as the sole stable products. EPR spectro scopy shows that persistent arylnitroxyl radicals are formed as interm ediates and then further photolyzed. A mechanism accounting for these observations is proposed. (C) 1996 Elsevier Science Ltd