SYNTHESIS AND CHIROPTICAL PROPERTIES OF AXIALLY CHIRAL, BINAPHTHOL-BASED OLIGOMERS

Authors
NG MK CHOW HF CHAN TL MAK TCW
Citation
Mk. Ng et al., SYNTHESIS AND CHIROPTICAL PROPERTIES OF AXIALLY CHIRAL, BINAPHTHOL-BASED OLIGOMERS, Tetrahedron letters, 37(17), 1996, pp. 2979-2982
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
17
Year of publication
1996
Pages
2979 - 2982
Database
ISI
SICI code
0040-4039(1996)37:17<2979:SACPOA>2.0.ZU;2-P
Abstract
Optically active, axially chiral binaphthol-based oligomers 2 to 4 wer e synthesized via Hay's coupling from the monomer 1. These oligomers e xhibited moderate optical rotation enhancement but the effect quickly reaches a plateau with the tetramer 4. (C) 1996 Elsevier Science Ltd