The atmospheres of novae at early times in their outbursts are very ex
tended, expanding shells with low densities. Models of these atmospher
es show that non-LTE effects are very important and must be included i
n realistic calculations. We have, therefore, been improving our atmos
pheric studies by increasing the number of ions treated in non-LTE. On
e of the most important ions is Fe II, which has a complex structure a
nd numerous lines in the observable spectrum. In this paper we investi
gate non-LTE effects for Fe II for a wide variety of parameters. We us
e a detailed Fe Ir model atom with 617 level and 13,675 primary lines,
treated using a rate-operator formalism. We show that the radiative t
ransfer equation in nova atmospheres must be treated with sophisticate
d numerical methods and that simple approximations, such as the Sobole
v method, cannot be used because of the large number of overlapping li
nes in the comoving frame.Our results show that the formation of the F
e II lines is strongly affected by non-LTE effects. For low effective
temperatures, T-eff < 20,000 K, the optical Fe II lines are most influ
enced by non-LTE effects, while for higher T-eff the UV lines of Fe II
are very strongly affected by non-LTE. The departure coefficients are
such that Fe II tends to be overionized in non-LTE when compared to L
TE. Therefore, Fe II non-LTE must be included with sophisticated radia
tive transfer in nova atmosphere models in order to analyze observed n
ova spectra reliably. Finally, we show that the number of wavelength p
oints required for the Fe II non-LTE model atmosphere calculations can
be reduced from 90,000 to about 30,000 without changing the results i
f we choose a sufficiently dense UV wavelength grid.