Ke. Treacher et al., NOVEL AMPHIPHILIC PHTHALOCYANINE MESOGENS, Molecular crystals and liquid crystals science and technology. Section A, Molecular crystals and liquid crystals, 260, 1995, pp. 255-260
A number of novel amphiphilic phthalocyanines (Pcs) have been prepared
containing long alkyl (-C16H33) and oligo(ethyleneoxy) chains (-O(C2H
4O)(3)CH3) in the peripheral positions. All the Pcs prepared showed li
quid crystalline behaviour, with most compounds giving two mesophases.
Optical microscopy suggests that the lower temperature mesophase (M1)
is a discotic rectangular mesophase, and that the higher temperature
mesophase (M2) is a discotic hexagonal phase.