TRANSLATIONAL ENERGY-DEPENDENCE OF THE REACTIVE CROSS-SECTION OF THE C-]CN+O REACTION STUDIED IN PULSED, CROSSED, SUPERSONIC MOLECULAR-BEAMS(NO)

Authors
COSTES M NAULIN C GHANEM N DORTHE G
Citation
M. Costes et al., TRANSLATIONAL ENERGY-DEPENDENCE OF THE REACTIVE CROSS-SECTION OF THE C-]CN+O REACTION STUDIED IN PULSED, CROSSED, SUPERSONIC MOLECULAR-BEAMS(NO), Journal of the Chemical Society. Faraday transactions, 89(10), 1993, pp. 1501-1504
Citations number
18
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Journal title
Journal of the Chemical Society. Faraday transactions → ACNP
ISSN journal
09565000
Volume
89
Issue
10
Year of publication
1993
Pages
1501 - 1504
Database
ISI
SICI code
0956-5000(1993)89:10<1501:TEOTRC>2.0.ZU;2-Y
Abstract
The C(3P(J)) + NO(X 2PI(r)) --> CN(X 2SIGMA+) + O(3P(J)) reaction is s tudied using combined pulsed lasers and pulsed, crossed, supersonic mo lecular beams. The relative reactive cross-section is found to decreas e slowly in the relative translational energy domain sampled, epsilon( tr) = 0.038 - 0.163 eV (1 eV almost-equal-to 1.602 18 x 10(19) J), wit h a dependence that can be fitted to a (epsilon(tr))-1/3 functionality .