MOLECULAR-HYDROGEN, MOLECULAR-NITROGEN AND MONOHYDRIDE DERIVATIVES OFTHE STRUCTURALLY CHARACTERIZED ETHYLANILINE)[TRIS(P-TOLYL)PHOSPHINE]RUTHENIUM(II) COMPLEX

Authors
MUDALIGE DC RETTIG SJ JAMES BR CULLEN WR
Citation
Dc. Mudalige et al., MOLECULAR-HYDROGEN, MOLECULAR-NITROGEN AND MONOHYDRIDE DERIVATIVES OFTHE STRUCTURALLY CHARACTERIZED ETHYLANILINE)[TRIS(P-TOLYL)PHOSPHINE]RUTHENIUM(II) COMPLEX, Journal of the Chemical Society, Chemical Communications, (10), 1993, pp. 830-832
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1993
Pages
830 - 832
Database
ISI
SICI code
0022-4936(1993):10<830:MMAMDO>2.0.ZU;2-R
Abstract
The crystallographically characterised, five-coordinate complex phenyl phosphino-N,N-dimethylaniline){P(p-tolyl)3}] reversibly binds H-2 and N2 to form eta2-H-2 and sigma-N2 species, respectively; the former rea cts with base to generate the chloro(hydrido) derivative.