ULTRAVIOLET-ABSORPTION SPECTRUM OF THE BENZYL CATION OBSERVED BY THE PULSE-RADIOLYSIS OF BENZYL-CHLORIDE

Authors
FUJISAKI N COMTE P GAUMANN T
Citation
N. Fujisaki et al., ULTRAVIOLET-ABSORPTION SPECTRUM OF THE BENZYL CATION OBSERVED BY THE PULSE-RADIOLYSIS OF BENZYL-CHLORIDE, Journal of the Chemical Society, Chemical Communications, (10), 1993, pp. 848-849
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
10
Year of publication
1993
Pages
848 - 849
Database
ISI
SICI code
0022-4936(1993):10<848:USOTBC>2.0.ZU;2-U
Abstract
The absorption spectrum of the benzyl cation has been found to have a strong band at 303 +/- 2 nm and a weak broad band near 500 nm by compa ring the transient spectrum for benzyl chloride saturated with oxygen with those for the solutions of 0.5 mol dm-3 ethanol in benzyl chlorid e saturated with oxygen.