The carbide layers produced by reaction of a Si(100) surface with a C2
H4 beam were analyzed by high resolution X-ray photoelectron spectrosc
opy (XPS). It was found that the reaction occurs above similar to 600
degrees C. The growth rate of the carbide layer at a beam flux of 2.7
x 10(15) molecules cm(-2) s(-1) increased with the surface temperature
up to 675 degrees C, and then decreased with increasing the temperatu
re. This phenomenon is explained in terms of the surface residence tim
e of the incident molecules and the diffusion rate of the Si atoms fro
m the substrate to the surface.