The interaction between ultrathin layers of Cu and Cr2O3(0001) surface
s was studied by X-ray photoelectron spectroscopy (XPS), Auger electro
n spectroscopy and low-energy electron diffraction (LEED). The XPS res
ults indicate that copper deposited on the Cr2O3(0001) surfaces is ini
tially in a Cu(I) state, and an agglomeration of copper on the Cr2O3(0
01)-1 x 1 surface was seen with increasing copper coverage. A Cu(111)R
30 degrees/Cr2O3(0001)-1 x 1 epitaxial relationship was observed by LE
ED.