P. Judeinstein et C. Sanchez, HYBRID ORGANIC-INORGANIC MATERIALS - A LAND OF MULTI-DISCIPLINARITY, Journal of materials chemistry, 6(4), 1996, pp. 511-525
Organic-inorganic hybrids appear as a creative alternative for obtaini
ng new materials with unusual features. This is related to their dipha
sic structures, leading to multifunctional materials. The low-temperat
ure processes which are used to synthesize such structures provide a w
ide versatility in the design of the compounds. The potentiality of th
e chemistry is to play on the structure of these mixtures and dissocia
te the various contributions in tailoring both phases and controlling
the interfaces. In this paper, a review of some chemistry pathways to
hybrid materials is presented. The nature of the bonds between organic
and inorganic phases is used to divide them in two major families: cl
ass I corresponds to materials with weak interphase bonding, while cla
ss II corresponds to materials where both phases are chemically grafte
d. Applications of these materials in the fields of optics, iono-elect
ronics, mechanics, biology and others are expected. Some applications
are reviewed, with respect to the versatility of the synthetic procedu
re. Most of the properties of these new high-technology materials are
dependent on their structural and chemical composition as well as on t
he dynamical properties inside the blends.