SOLVOTHERMAL SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE FIRST AMMONIUM COBALT GALLIUM PHOSPHATE HYDRATE, NH4[COGA2P3O12(H2O)(2)]

Authors
CHIPPINDALE AM COWLEY AR WALTON RI
Citation
Am. Chippindale et al., SOLVOTHERMAL SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE FIRST AMMONIUM COBALT GALLIUM PHOSPHATE HYDRATE, NH4[COGA2P3O12(H2O)(2)], Journal of materials chemistry, 6(4), 1996, pp. 611-614
Citations number
20
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
6
Issue
4
Year of publication
1996
Pages
611 - 614
Database
ISI
SICI code
0959-9428(1996)6:4<611:SSASCO>2.0.ZU;2-2
Abstract
The first ammonium cobalt gallium phosphate hydrate, NH4[CoGa2P3O12(H2 O)(2)] has been prepared under solvothermal conditions and the structu re determined using single-crystal X-ray diffraction [space group C2/c , a = 13.323(3), b = 10.245(1), c = 8.886(2) Angstrom, beta = 108.43(2 )degrees, V = 1150.68 Angstrom(3), Z = 4]. The structure consists of G aO5, CoO6 and PO4 polyhedra linked to form a microporous three-dimensi onal framework containing channels in which the NH4+ cations reside.