GENERATION OF RHODIUM CARBENOIDS ON A POLYSTYRENE SUPPORT AND THEIR OH-INSERTION REACTION WITH ALCOHOLS

Authors
ZARAGOZA F PETERSEN SV
Citation
F. Zaragoza et Sv. Petersen, GENERATION OF RHODIUM CARBENOIDS ON A POLYSTYRENE SUPPORT AND THEIR OH-INSERTION REACTION WITH ALCOHOLS, Tetrahedron, 52(16), 1996, pp. 5999-6002
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
16
Year of publication
1996
Pages
5999 - 6002
Database
ISI
SICI code
0040-4020(1996)52:16<5999:GORCOA>2.0.ZU;2-I
Abstract
A rhodium carbenoid attached to a polystyrene resin was generated by t reatment of a resin-bound diazoacetamide with rhodium(II) acetate in d ichloromethane. This immobilized reactive species underwent OH-inserti on reactions with alcohols to yield ethers of high purity. Copyright ( C) 1996 Elsevier Science Ltd