Microemulsions may have very different microstructures: discrete water
or oil droplets and bicontinuous - depending, inter alia, on the surf
actant polarity, salinity, temperature, and co-surfactant. A review is
given on structure determination of microemulsions of different syste
ms and the conditions for occurrence of different structures. Polymer
addition may dramatically influence microemulsion stability and struct
ure and examples are given for different types of polymers and discuss
ed on the basis of mixed solutions of polymers and surfactants in gene
ral.