MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .154. METHYLRHENIUM(V) OXO COMPLEXES - DERIVATIVES OF DI(4-T-BUTYLPYRIDINE) DICHLOROMETHYLOXORHENIUM(V)

Authors
HERRMANN WA RAUCH MU ROESKY PW
Citation
Wa. Herrmann et al., MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .154. METHYLRHENIUM(V) OXO COMPLEXES - DERIVATIVES OF DI(4-T-BUTYLPYRIDINE) DICHLOROMETHYLOXORHENIUM(V), Journal of organometallic chemistry, 511(1-2), 1996, pp. 299-302
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
511
Issue
1-2
Year of publication
1996
Pages
299 - 302
Database
ISI
SICI code
0022-328X(1996)511:1-2<299:MBBMEA>2.0.ZU;2-8
Abstract
Di(4-t-butylpyridine)dichloromethyloxorhenium(V) (1) is obtained by re ductive halogenation of methyltrioxorhenium(VII) in the presence of t- butylpyridine. A number of new methylrhenium(V) complexes can be synth esized by substitution of the halide and/or pyridine ligands, e.g. wit h chelating N- and P-bases or Schiff base ligands. The new rhenium com plexes exhibit an asymmetric coordination of the ligands.