A CONVENIENT ONE-POT SYNTHESIS OF (E)-SILYLATED CONJUGATED ENYNES FROM 1,1-BIS(TRIMETHYLSILYL)-2-PROPYNE AND CARBONYL DERIVATIVES

Authors
PORNET J PRINCET B MEVAA LM MIGINIAC L
Citation
J. Pornet et al., A CONVENIENT ONE-POT SYNTHESIS OF (E)-SILYLATED CONJUGATED ENYNES FROM 1,1-BIS(TRIMETHYLSILYL)-2-PROPYNE AND CARBONYL DERIVATIVES, Synthetic communications, 26(11), 1996, pp. 2099-2111
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synthetic communications → ACNP
ISSN journal
00397911
Volume
26
Issue
11
Year of publication
1996
Pages
2099 - 2111
Database
ISI
SICI code
0039-7911(1996)26:11<2099:ACOSO(>2.0.ZU;2-7
Abstract
1,1-Bis(trimethylsilyl)-2-propyne, prepared from propargyltrimethylsil ane, was reacted, in the presence of a Lewis acid, with electrophiles (aldehydes, acetals) to afford (E)-silylated conjugated enynes.