An experimental and numerical study was performed to characterize the
structure of diffusion flames stabilized in the mixing layer formed be
tween counterflowing streams of hydrogen diluted with nitrogen and air
diluted with nitrogen. Measurements were made with 15% to 30% hydroge
n by volume in the fuel stream. The concentration of the reactants in
the counterflowing streams as a function of their velocity at flame ex
tinction was recorded over a wide parametric range. Using a UV Raman s
cattering system, the profiles of the mass fraction of the species H-2
, O-2, H2O and N-2 and the temperature profiles were measured at two c
onditions, one close to and the other far from the critical conditions
of extinction, Numerical calculations using detailed chemistry were p
erformed to predict the flame structure and the results were found to
agree well with the measurements. It is found that the chemical-kineti
c mechanism employed here can accurately describe the combustion of hy
drogen.