MODELS OF CYTOCHROMES-B CONTAINING AN ORGANOMETALLIC AXIAL BASE, AZAFERROCENE - SYNTHESIS AND ELECTRON-PARAMAGNETIC-RESONANCE STUDY

Authors
ZAKRZEWSKI J GIANNOTTI C
Citation
J. Zakrzewski et C. Giannotti, MODELS OF CYTOCHROMES-B CONTAINING AN ORGANOMETALLIC AXIAL BASE, AZAFERROCENE - SYNTHESIS AND ELECTRON-PARAMAGNETIC-RESONANCE STUDY, Journal of the Chemical Society. Dalton transactions, (10), 1993, pp. 1629-1630
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
10
Year of publication
1993
Pages
1629 - 1630
Database
ISI
SICI code
0300-9246(1993):10<1629:MOCCAO>2.0.ZU;2-8
Abstract
Azaferrocene reacted with [Fe(oep)(O3SCF3)] or [Fe(tpp)(O3SCF3)] (oep = 2,3,7,8,12.13,17,18-octaethylporphyrinate; tpp = 5,10,15,20-tetraphe nylporphyrinate to afford [Fe(oep){Fe(C5H5)(C4H4N}2]O3SCF3 or [Fe(tpp) {Fe(C5H5)(C4H4N)}2]O3SCF3, respectively; the trinuclear complexes exhi bit rhombic low-spin EPR spectra indicating the strong ligating abilit y of azaferrocene.